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UN identification number

UN3365: Trinitrochlorobenzene

As listed: Trinitrochlorobenzene (picryl chloride), wetted, with not less than 10% water by mass

UN3365 appears 1 time in the Hazardous Materials Table (49 CFR §172.101). Hazard class 4.1, packing group I.

ID numberUN3365
Hazard class4.1
Packing groupI
Label codes4.1

All §172.101 entries for UN3365

Open any entry for packaging sections, special provisions, air limits and vessel stowage.

What it means

4.1
Class 4.1 — Flammable solid. Solids that ignite readily or can cause fire through friction, plus self-reactive and desensitized explosive materials.

Packing group ranks danger within the class: PG I = great danger.

Label codes (column 6): 4.1 → Flammable solid label.

UN numbers are recognized for international and domestic transport.

Example basic description

UN3365, Trinitrochlorobenzene (picryl chloride), wetted, 4.1, PG I

Proper shipping name shown without the table's italic descriptive text. Order per §172.202: ID number, proper shipping name, hazard class, packing group. Example only — add technical names, “RQ”, quantities and other elements your shipment requires.

What to check next

  1. Match the name. Compare your SDS Section 14 to the proper shipping names above and pick the row with your packing group.
  2. Read the special provisions on the entry page (§172.102) — they can add limits or exceptions.
  3. Check packaging — the entry page lists the Part 173 sections for exceptions, non-bulk and bulk.
  4. Labels & placards. Placarding depends on class and quantity — see Table 1 vs Table 2.
  5. Emergency response. Find the response guide for UN3365 in the current PHMSA Emergency Response Guidebook.
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Common questions about UN3365

What is UN3365?

UN3365 is the identification number for Trinitrochlorobenzene (picryl chloride), wetted in the DOT Hazardous Materials Table (49 CFR §172.101).

What hazard class is UN3365?

UN3365 is listed under hazard class 4.1 (flammable solid).

What packing group is UN3365?

Packing group for UN3365: I. Where several rows exist, the packing group that fits your material decides which row applies.

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Source: Hazardous Materials Table (49 CFR §172.101), eCFR.gov — current as of Oct 23, 2026. View the official table. Reference only — verify current requirements before shipping.